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Publications


  1. Electronic Modification of a Sterically Demanding Anionic Pyridine Ligand.
    N. M. C. Schmidlin, V. Radtke, A. Schmidt, M. Lõkov, I. Leito, T. Böttcher, Z. Anorg. Allg. Chem., 2022, accepted.
    DOI: 10.1002/zaac.202200136
  1. Reaction of 2,6-Bis(diazaboryl)pyridine with Alkyls of Lithium, Zinc and Magnesium.
    V. M. L. Rommel, J. M. Fix, T. Böttcher, Z. Anorg. Allg. Chem., 2022, accepted.
    DOI: 10.1002/zaac.202100361
  1. Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine-B(C6F5)3 Lewis Pair.
    J. Lin, F. Wossidlo, N. T. Coles, M. Weber, S. Steinhauer, T. Böttcher, C. Müller, Chem. Eur. J., 2022, 28, e202104135.
    DOI: 10.1002/chem.202104135
    Front Cover: 10.1002/chem.202200174
  1. Chromium(II) Alkylcyclopentadienyl Complexes with Carbon or Hydride Donor Ligands.
    I. Smytschkow, W. Gidt, Y. Sun, J. Langer, T. Böttcher, L. Kubíčková, O. Kaman, H. Sitzmann, Organometallics, 2021, 40, 2951-2969.
    DOI: 10.1021/acs.organomet.1c00159
  1. Making Aromatic Phosphorus Heterocycles more Basic and Nucleophilic: Synthesis, Characterization and Reactivity of the First Phosphinine Selenide.
    F. Wossidlo, D. Frost, J. Lin, N. T. Coles, K. Klimov, M. Weber, T. Böttcher, C. Müller, Chem. Eur. J., 2021, 27, 12788-12795.
    DOI: 10.1002/chem.202102390
    Front Cover: 10.1002/chem.202102859
  1. Cations and Anions of Dibenzo[a,e]pentalene and Reduction of a Dibenzo[a,e]pentalenophane.
    M. Hermann, T. Böttcher, M. Schorpp, S. Richert, D. Wassy, I. Krossing, B. Esser, Chem. Eur. J., 2021, 27, 4964-4970.
    DOI: 10.1002/chem.202005131
  1. Isolation and characterization of a lithiated pyridine – aggregation in the solid state and in solution.
    N. M. C. Schmidlin, H. Scherer, A. Hoffmann and T. Böttcher, Chem. Commun. 2020, 56, 4160-4163.
    DOI: 10.1039/D0CC01355B
    Inside Front Cover: 10.1039/D0CC90161J
    Hervorgehoben in "Trendbericht Anorganische Chemie: Hauptgruppen", Nachr. Chem. 2021, 69, 52-66.
  1. 2,6-Bis(diazaboryl)pyridine – A Ligand with Hemilabile Donor and Lewis-Acid Functionalities.
    J. Schröder, T. Böttcher, Eur. J. Inorg. Chem., 2020, 342-348.
    DOI: 10.1002/ejic.201901164
    Front Cover: 10.1002/ejic.202000013
    Cover Profile: 10.1002/ejic.202000014
  1. Chromium(III) and Chromium(II) Phenolate Complexes with Bulky Alkylcyclopentadienyl Ligands.
    I. Smytschkow, W. Gidt, C. Kunz, Y. Sun, J. Langer, B. Oelkers, T. Böttcher, H. Sitzmann, Eur. J. Inorg. Chem. 2019, 22, 2742-2749.
    DOI: 10.1002/ejic.201900275
  1. Isolation of a Stable Pyridine Radical Anion.
    J. Schröder, D. Himmel, D. Kratzert, V. Radtke, S. Richert, S. Weber, T. Böttcher, Chem. Commun. 2019, 55, 1322-1325.
    DOI: 10.1039/c8cc09700c
    Hervorgehoben in "Trendbericht Anorganische Chemie: Hauptgruppen", Nachr. Chem. 2020, 68, 50-64.
  1. Paramagnetic Chromium(II) Complexes and Chromium(IV) Nitrides with Bulky Alkylcyclopentadienyl Ligands
    W. Gidt, I. Smytschkow, Y. Sun, J. Langer, T. Böttcher, D. Kratzert, J. Klingele, B. Oelkers, H. Sitzmann, Eur. J. Inorg. Chem. 2018, 4472-4480.
    DOI: 10.1002/ejic.201800901
  1. [4-(Ph3B)-2,6-Mes2Py]-: A Sterically Demanding Anionic Pyridine.
    N. M. C. Schmidlin, M. Lõkov, I. Leito, T. Böttcher, Chem. Eur. J., 2018, 24, 16851-16856.
    DOI: 10.1002/chem.201803626
    Hervorgehoben in "Trendbericht Anorganische Chemie: Hauptgruppenelemente", Nachr. Chem. 2019, 67, 46-64.
  1. 2,6-Bis(diazaboryl)pyridine: A Superbasic Sterically Demanding Pyridine Ligand.
    J. Schröder, D. Himmel, T. Böttcher, Chem. Eur. J., 2017, 23, 10763-10767.
    DOI: 10.1002/chem.201702890
    Hervorgehoben in: "Trendbericht Anorganische Chemie 2017: Hauptgruppenelemente", Nachr. Chem. 2018, 66, 209-229.
  1. Synthesis and crystal structures of extremely bulky phosphinoamido and phosphinoamino germanium(II) chloride complexes.
    T. Böttcher, C. Jones, Main Group Metal Chem., 2015, 5-6, 165-168.
    DOI: 10.1515/mgmc-2015-0026
  1. Extremely bulky secondary phosphinoamines as substituents for sterically hindered aminosilanes.
    T. Böttcher, C. Jones, Dalton Trans., 2015, 44, 14842-14853.
    DOI: 10.1039/C5DT02504D
  1. Highly reactive carbenes as ligands for main group element fluorides. Syntheses and applications.
    T. Böttcher, G.-V. Röschenthaler, J. Fluorine Chem., 2015, 171, 4-11.
    DOI: 10.1016/j.jfluchem.2014.10.018
  1. NHC-SiCl4: An Ambivalent Carbene-Transfer Reagent.
    T. Böttcher, S. Steinhauer, L. C. Lewis-Alleyne, B. Neumann, H.-G. Stammler, B. S. Bassil, G.-V. Röschenthaler and B. Hoge, Chem. Eur. J., 2015, 21, 893-899.
    DOI: 10.1002/chem.201404628
  1. Synthesis of Chlorosilicates.
    S. Steinhauer, T. Böttcher, N. Schwarze, B. Neumann, H.-G. Stammler and B. Hoge, Angew. Chem. Int. Ed., 2014, 53, 13269-13379.
    DOI: 10.1002/anie.201406311
    Synthese von Chlorosilikaten.
    Angew. Chem., 2014, 126, 13485-13488.
    DOI: 10.1002/ange.201406311
  1. Selective synthesis of cis- and trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4.
    L. C. Lewis-Alleyne, B. S. Bassil, T. Böttcher and G.-V. Röschenthaler, Dalton Trans., 2014, 43, 15700-15703.
    DOI: 10.1039/c4dt02214a
  1. Pentacoordinate Silicon(IV): Cationic, Anionic and Neutral Complexes Derived from the Reaction of NHC→SiCl4 with Highly Lewis Acidic (C2F5)2SiH2.
    T. Böttcher, S. Steinhauer, B. Neumann, H.-G. Stammler, G.-V. Röschenthaler, and B. Hoge, Chem. Commun., 2014, 50, 6204-6206.
    DOI: 10.1039/c4cc02583k
    Inside Back Cover: DOI: 10.1039/c4cc90179g
  1. Syntheses of novel delocalized cations and fluorinated anions, new fluorinated solvents and additives for lithium ion batteries.
    T. Böttcher, B. Duda, N. Kalinovich, O. Kazakova, M. Ponomarenko, K. Vlasov, M. Winter, G.-V. Röschenthaler, Prog. Solid State Chem., 2014, 42, 202-217.
    DOI: 10.1016/j.progsolidstchem.2014.04.013
  1. Carbene Complexes of Phosphorus(V) Fluorides substituted with Perfluoroalkyl-groups Synthesized by Oxidative Addition. Cleavage of the Complexes by HF reveals a new Synthetic Protocol for Ionic Liquids.
    T. Böttcher, S. Steinhauer, N. Allefeld, B. Hoge, B. Neumann, G. Stammler, B. Bassil, M. Winter, N. W. Mitzel, and G.-V. Röschenthaler, Dalton Trans., 2014, 43, 2979-2987.
    DOI: 10.1039/c3dt53043d
  1. Synthesis and Characterization of Novel Carbene Complexes of Phosphorus(V) Fluorides with Potential Liquid-Crystalline Properties.
    R. Pajkert, T. Böttcher, M. Ponomarenko, M. Bremer, G.-V. Röschenthaler, Tetrahedron, 2013, 69, 8943–8951.
    DOI: 10.1016/j.tet.2013.07.062
  1. Phosphorus(V) Complexes with Acyclic Monoaminocarbene Ligands via Oxidative Addition.
    T. Böttcher, B. S. Bassil, L. Zhechkov, and G.-V. Röschenthaler, Inorg. Chem., 2013, 52, 5651-5653.
    DOI: 10.1021/ic400756z
  1. (NHCMe)SiCl4: A Versatile Carbene Transfer Reagent - Synthesis From Silicochloroform.
    T. Böttcher, B. S. Bassil, L. Zhechkov, T. Heine and G.-V. Röschenthaler, Chem. Sci., 2013, 4, 77-83.
    DOI: 10.1039/c2sc21214e
    Inside Front Cover: DOI: 10.1039/c2sc90052a
  1. Carbene Adduct as Overcharge Protecting Agent in Lithium Ion Batteries.  
    C. Dippel, R. Schmitz, R. Müller, T. Böttcher, M. Kunze, A. Lex-Balducci, G.-V. Röschenthaler, S. Passerini and M. Winter, J. Electrochem. Soc. 2012, 159, A1587-A1590.
    DOI: 10.1149/2.006210jes
  1. Carbene Complexes of Phosphorus(V) Fluorides by Oxidative Addition of 2,2-Difluorobis(dialkylamines) to Phosphorus(III) Halides.
    T. Böttcher, O. Shyshkov, M. Bremer, B. S. Bassil, and G.-V. Röschenthaler, Organometallics 2012, 31, 1278-1280.
    DOI: 10.1021/om2009827
  1. Complexes of Ge(IV)- and Sn(IV)-Fluorides with Cyclic and Acyclic Carbenes: Bis(dialkylamino)-difluoromethylenes as Carbene Sources.
    T. Böttcher, B. S. Bassil, and G.-V. Röschenthaler Inorg. Chem. 2012, 51, 763-765.
    DOI: 10.1021/ic202008m